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Showing posts from February, 2022

"MISSION GANGA NOT UP TO THE MARK" SAYS THE STUDENTS

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"MISSION GANGA NOT UP TO THE MARK," SAYS THE STUDENTS "Mission Ganga is not efficient and not up to the mark," says the students. The Indian embassy at Keiv is not coordinating anything that the Indians need when they are trapped on the battlefield.  The Indian embassy is not providing any travel ways or rescue missions with the joining hands of the native government  The mission is aligned with Hungary, Poland , Romania, and the Slovak republic. The students in KYIV and KARKEIV are in danger. Poland and all the other country is too far away from these place if the Indian government-aligned and opened the border of Russia it would be more useful for the rescue mission.  It will be too hard to travel 1500km to reach the Poland border in a country marshal law is initiated and it is literally impossible without any strategic support from the native government. Still, there are thousands of students trapped in the capital Kyiv 

HIGH PERFORMANCE LIQUID CHROMATOGRAPHY

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 HIGH-PERFORMANCE LIQUID CHROMATOGRAPHY It is a method used for the separation, purification, and identification of various nonvolatile high molecular weight organic compounds and natural products like cholesterol, terpenoids. ADVANTAGES High-speed separation Excellent column separation Solvent consumption is minimum Sensitive and accurate Separation can be done at an ambient temperature. PRINCIPLE The components of the mixture are separated depending upon the extent of adsorption and partition on the stationary phase and the rate at which the component is carried by the mobile phase. The mobile phase is liquid and the stationary phase can be solid or liquid. INSTRUMENTATION Solvent reservoirs are used to collect the different solvents. Pressure pump to apply pressure  Sample injector to give the mixture which is to be separated in the analytical column Regulator to adjust the flow rate Guard column to remove the particulate matter and contaminants from the solvent. The analytical colu

THIN LAYER CHROMATOGRAPHY

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 THIN LAYER CHROMATOGRAPHY It is a chromatographic separation method used to separate mixtures, to check the purity of a mixture, and to monitor the progress of the reaction. Procedure A glass plate coated with a material of the adsorbent will constitute the stationary phase. The material is made into a slurry or a paste and the glass plate is coated with it by a thin layer applicator and dried. This glass plate with a thin layer of stationary phase is called chromatoplate. The mixture to be separated is applied to one end of the plate and it is placed in the solvent. When the solvent reaches near the top, it is removed and dried. If the components are colored the spots can be readily located. If the components are colorless the dried plate is sprayed with a suitable reagent to make the spot colored. In this way, the position of the components is located and their Rf values are determined. Rf value is the ratio of the distance traveled by a component to the distance traveled by the sol

COLUMN CHROMATORGAPHY

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 COLUMN CHROMATOGRAPHY It is a technique in which the stationary phase is solid or a liquid supported by a solid. When a column is used as the adsorbent it is called adsorption column chromatography. When the solid column is acting only as a support to the liquid adsorbent then it is called partition column chromatography. SEPARATION The selection of solvent is based on the nature of the components in the mixture. Adsorption depends upon the nature of the solvent and the adsorbent.  The rate at which the components of a mixture are separated depends upon the activity of the adsorbent and the polarity of the solvent. If the activity of the adsorbent is very high and polarity is low, then separation is low but gives good separation. If the activity of the adsorbent is low and the polarity of the solvent is high, then the separation is rapid but gives poor separation PROCEDURE A proper adsorbent is selected and made a slurry with a suitable liquid and placed in a suitable tube which is pl

CHROMATOGRAPHY

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CHROMATOGRAPHY  It is a method used for the separation, purification, and identification of a mixture of substances. It is useful when components of a mixture have similar physical and chemical properties and hence cannot be separated by other methods. Principle: It is based on the distribution of the components in a mixture between a stationary and a mobile phase. The stationary phase may be a column of adsorbent, a paper, a thin layer of adsorbent through which the mobile phase moves on. The mobile phase may be a liquid or gas. The principle of chromatographic separation is always adsorption (absorption of a constituent on the surface of the solid stationary phase) or partition (distribution of a constituent in between two liquid stationary phases). THEORY OF CHROMATOGRAPHY The separation takes place due to the differential migration of components which depends on the relative affinity towards the stationary and mobile phases.  The component which is less strongly held by the station

AUSTRALIA OPENS THERE INTERNATIONAL BORDER

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 AUSTRALIA OPENS THERE INTERNATIONAL BORDER Australia will open its border on 21st February They are opening their border after 2 years It will be more helpful for students and foregoing working professionals  Australia will reopen its borders on 21st February for fully vaccinated tourists, said Scott Morrison the Prime Minister of Australia. Australia shuts there border in March 2020 to protects itself from the covid 19 virus from then there was a handful of tourists were allowed to enter the country  This decision would be more helpful for the students and the foreign working professionals who had been working or studying there for 2 years There will be a need for full vaccination and RTPCR test results within the last 48 hours for tourists 

COVID19-DENMARK

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COVID19- DENMARK Denmark lifts all their COVID19 restriction Denmark opens their border for TRAVELERS All the covid vaccinated travelers who have EU visas can enter DENMARK Denmarks opens their borders for visitors from the world they can travel anywhere in Denmark without any restriction of covid 19. From February 19 Denmark is open for every who has got vaccinated. Denmark withdrawals all there need for social distancing, mask-wearing, and quarantine for those who tested positive for covid 19. Denmark is the first country to lift all the covid 19 restrictions. The Government of Denmark took off its digital COVID pass and the mask is only required in hospitals The Danish authorities last month the list of vaccines entering was expanded with four additional vaccines Covisheild  Covaxin Sinovac Sinopharm " Two years into the pandemic, populations in most countries have reached a high level of immunity from vaccines or natural illness " Danish epidemiologist Lone Simonsen of Un

DIFFERENTIAL THERMAL ANALYTICS

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 DIFFERENTIAL THERMAL ANALYTICS  It is a thermal analytic technique that can be used as a fingerprint for the identification of different materials like clays, minerals, cement, etc. DTA allows the detection of every chemical and physical change whether or not it is accompanied y a change in weight. In DTA, the temperature of the samples and a thermally inert reference material are measured as a function of temperature. The differential temperature (∆T) vs the programmed temperature (T) gives the temperature at which the transition occurs and whether the transition is exothermic or endothermic.

THERMOGRAVIMETRIC ANALYSIS

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 THERMOGRAVIMETRIC ANALYSIS It is a thermal analytic technique in which the mass of a substance is measured as a function of increasing temperature. As the temperature increases, the sample undergoes physical and chemically changed will be accompanied by mass loss.  It is used to determine a material’s thermal stability and its fraction of volatile components by measuring the weight change.  It is carried out in air or inert atmosphere such as nitrogen, helium, or Argon.  The graph obtained is known as a thermogram. It is a plot of mass vs temperature. It can provide information about physical phenomena such as vaporization, sublimation. Absorption, adsorption, and desorption. And chemical phenomena like chemisorption, dehydration, decomposition, oxidation, and reduction.  WORKING OF TGA The sample is placed in a crucible or shallow dish that is attached to an automatic recording balance and is continuously heated by the power source. The weight change of the sample is converted into a

NMR SPECTROSCOPY

 NMR SPECTROSCOPY  NMR depends on the absorption of energy when the nucleus of an atom is excited from its lowest energy nuclear spin state to the next higher one.  The nuclear energy levels are produced by keeping nuclei in a magnetic field. The NMR spectrum is produced by EM radiation in the radio wave frequency region (60-500MHz).  NMR spectroscopy deals with nuclei having I=1/2. The spin quantum number (I) is related to the atomic number and mass number of the nucleus. Elements with either odd mass numbers or add atomic numbers have the property of nuclear spin. Radio waves are the lowest energy form of EM radiation. This energy is too small to vibrate, rotate or excite an atom or molecule. It is sufficient to influence the nuclear spin of the atoms of a molecule.  Principle of NMR The nucleus of an atom is positively charged, when it spins it develops a magnetic field and acts like a tiny bar magnet with a magnetic moment (µ) µ= I(I+1)1/2 h/2 π  The spin quantum number of the nucl